Everything I’ve read indicates the top of the hood is a high pressure area. So vents there won’t help without large spoilers to create a low pressure area behind them and disrupt the boundary layer. If you look at the WRC cars you will see the vents on the side extremities of the hood for that reason.
Yes, however, the pressure isn't constant across the entire hood. The underhood pressure is still greater than the pressure over the hood, therefore, the flow would still be from a high pressure to a lower pressure, even if the pressure over the hood is higher than other areas of the exterior. For the most part, the overall hood can be considered a lower pressure area. There are some good CFD images showing how the pressure is different over the hood, and that difference will change from car to car based on the design. It has been awhile since the last time I read over my aerodynamics book on underhood air flow, but this is how I recall the information. To help promote a low pressure area, most hood vents have a flap on the leading edge to break up the boundary layer and create a localized lower pressure. I also think the WRC cars have underhood ducting that takes the heat from the radiator and isolates it until it gets to the hood vents. They also have a lot more room in the engine compartment to run ducting. If you look at the last few decades worth of WRC cars, it is interesting to see how many different types of heat extraction vents have been used. The 2003-2005ish Focus WRC had the radiator mounted almost flat and ducting going into the radiator from the bumper, a set of twin fans in a shroud on top of the radiator, and then a boxed section on the hood that sealed the radiator to the extraction vents. Subaru has done similar things with their radiators and it works well with the boxer engine being so much lower in the chassis. For a street car, adding a set of hood vents with a leading edge flap would still be effective. I have seen a number of Fiestas use the MkII Focus RS vents. They look great on the car and work as well.
You are 100% right on the NACA ducts. They bring air in, not air out. Not many people get that one, so I am impressed.